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Aging of porous silicon and the origin of blue shift

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Abstract

Aging effects of porous silicon (PS) and the origin of blue shift are investigated. Photoluminescence (PL) measurements of the PS prepared with HF-EtOH solution showed a 210 meV blue shift after 1.5 months. It is found from deconvolution of the PL spectra that this shift is not fully related to the quantum confinement (QC) effect. For stable PS formation, a HF-EtOH-H2O2 solution is used. A stable luminescence at 2.01 eV with a Gaussian distribution is obtained when the samples are kept in H2O2 for 45 min after the anodization.

©2003 Optical Society of America

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Figures (5)

Fig. 1.
Fig. 1. Simplified cross-sectional drawing of anodization cell. The designed cell provided practical wax-free sample mounting.
Fig. 2.
Fig. 2. Variation of aging of normalized PS luminescence with time, formed by HF:EtOH.
Fig. 3.
Fig. 3. Variation of aging of PS luminescence, formed by HF:EtOH, with time. (a) After 1 h, (b) after 1 day, (c) after 2 days, (d) after 2 wk, (e) after 1.5 months
Fig. 4.
Fig. 4. Variation of aging of PS luminescence with time, formed by 6HF:4EtOH:H2O2 (as measured).
Fig. 5.
Fig. 5. Variation of aging of PS luminescence with time. PS is formed by 6HF:4EtOH:H2O2 solution and kept in H2O2 for 45 min.
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